Normally I would recommend games based on individual tastes, but throwing that aside for argument’s sake, and the topic, I’m going to assume the person I’m recommending games only has a PS2, therefore he/she is limited only to PS2 and PS1 games, as well as has a PC for the sake of emulation. In that scenario, I would try to keep it simple and recommend games I’ve played myself that aren’t overly complicated, but can in turn potentially open the floodgates for that person to go out and seek out more games to play.
I would recommend:
• Kirby's Adventure
• Super Mario World
• StarFox (SNES)
• Mega Man X
• Pokémon Yellow Version
• Twisted Metal 2
• Metal Gear Solid
• Ico / Shadow of the Colossus
• Capcom Classics Collection
• Jak and Daxter: The Precursor Legacy
The first game I listed was actually Tetris, but I personally would rather prefer a novice have a far more interactive and dynamic gaming experience, they can easily pick up a puzzle game at a later time; I feel most people have experienced puzzlers one way or another in their life, anyway. Overall, I believe these games are a good balance for a newcomer, especially with the diversity that Capcom Classics Collection offers. I actually chose Volume 2 instead, but decided against it; and was initially going to include Taito Legends 2 in the list, but one compilation title is enough, plus I feel Capcom Classics Collection is a bit more cohesive (if I’m even making sense by saying that). And yes, I reckon I’m kind of cheating by choosing a compilation game, but it has some truly worthwhile titles that I’m sure a newcomer would greatly enjoy. I also know I’m cheating by bundling Ico and Shadow of the Colossus together, but anyone that has played both knows where I’m going with that. In a way, you can’t have one without the other, and I’m sure a newbie will enjoy the experience of playing both, one after the other. I would’ve included Katamari Damacy and Ōkami in the list, as I feel they both would be a nice choice for a beginner, but I’ve yet to play them to feel comfortable enough to recommend them. I also think Spyro the Dragon and Crash Bandicoot are strong choices, but I already selected various platformers. Lastly, I refrained from including strenuous RPGs since I believe it would be better for a person experiencing video games for the very first time to be introduced to the genre as gingerly as possible, thus why I chose Pokémon Yellow.
And that's it.